I like using /sbin/ip for these kind of tasks, because it is far easier to parse:
$ ip link show eth0
2: eth0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast qlen 1000
link/ether 00:0c:29:30:21:48 brd ff:ff:ff:ff:ff:ff
You can trivially get the mac address from this output with awk:
$ ip link show eth0 | awk '/ether/ {print $2}'
00:0c:29:30:21:48
If you want to put a little more effort in, and parse more data out, I recommend using the -online argument to the ip command, which will let you treat every line as a new device:
$ ip -o link
1: lo: <LOOPBACK,UP,LOWER_UP> mtu 16436 qdisc noqueue \ link/loopback 00:00:00:00:00:00 brd 00:00:00:00:00:00
2: eth0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast qlen 1000\ link/ether 00:0c:29:30:21:48 brd ff:ff:ff:ff:ff:ff
3: eth1: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast qlen 1000\ link/ether 00:0c:29:30:21:52 brd ff:ff:ff:ff:ff:ff
4: tun0: <POINTOPOINT,MULTICAST,NOARP,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast qlen 100\ link/[65534]
5: sit0: <NOARP> mtu 1480 qdisc noop \ link/sit 0.0.0.0 brd 0.0.0.0