No, definitely not. This suggestion that DVCSes would not be suitable for the enterprise is pertinently false, a common FUD argument from people who for whatever reason have a desire not to abandon SVN.
In actuality, also in enterprise settings DVCSes give you many benefits:
- Ability to check in frequently without risking blocking other people
- Offline working
- High performance
- Effective branching/merging
- Pull access pattern
With regard to that last one, you can give seasoned developers direct push access to the main repository, while for new or junior members their mentor pulls from them and review their changes before pushing them.
Tying in to the discussion in the answer above; in this way DVCSes give you more control over your repository, while with SVN generally the only real workable model is to give all contributors commit access to at least parts of the code.
You may have less fine-grained control over permissions for sections with the code, however you can give different groups (e.g. documentation team) their own clone of the main repository, and merge it back periodically after review. Or put the documentation in a whole different repository altogether.
Often you need to un-learn practices you learned with centralized VCSes, go back to the use cases and what it is that you want to do, and then consider how a DVCS could empower this.
A very good article to read to get insight in the differences between version control systems is Making Sense of Revision-Control Systems.