I'm not sure if this answer is going to help you... but do you know how to harvest debugging information from Ghostscript on the commandline? Simply add "-dDEBUG" to the commandline and it will spit out lots of additional info. To get debugging info from only specific topics, you have these options:
-dCCFONTDEBUG Compiled-in Fonts
-dCFFDEBUG CFF Fonts
-dCMAPDEBUG CMAP
-dDOCIEDEBUG CIE color
-dEPSDEBUG EPS handling
-dFAPIDEBUG Font API
-dINITDEBUG Initialization
-dPDFDEBUG PDF Interpreter
-dPDFOPTDEBUG PDF Optimizer (Linearizer)
-dPDFWRDEBUG PDF Writer
-dSETPDDEBUG setpagedevice
-dSTRESDEBUG Static GS Resources
-dTTFDEBUG TTF Fonts
-dVGIFDEBUG ViewGIF
-dVJPGDEBUG ViewJPEG
Possibly, a PostScript programmer guru could write a little PostScript program that could do what you want by re-defining one of the operators (showglyph?) in a way that it prints out the info you want instead of (or before) drawing each individual character and run that against your target PS file.
Maybe you should ask your question in comp.text.pdf or in comp.lang.postscript ?