In their homepage, at the Tour you can see a partial list of office, tools and games that already run OK (or more or less) at ReactOS. If you subscribe to the newsletter, you'll receive info about much more - for instance, I was quite surprised when I read most SQL Server 2000 tools actually work on ReactOS!! Query Analyzer, OSQL and Books Online work fine, Enterprise Manager and Profiler are buggy and the DBMS won't work at all.
At a former workplace (an all MS shop) we investigated seriously into it as a way to reduce our expenditure in licenses whilst keeping our in-house developed apps. Since it couldn't run MSDE fine, we had to abandon the project - hope in the future this will be solved and my ex-coworkers can push it again.
These announcements might as well be also on their homepage - I couldn't find them after 5 mins. of searching, though. Probably the easiest way to know all these compatibility issues is to join the newsletter, or look for its archives.
I have been tracking this OS' progress for quite some time. I believe it has all the potential to really bring an OSS operating system to the masses for it breaks the "chicken and egg" problem: it has applications and drivers from the very beginning (since it aims to have full ABI compatibility with MS Windows).
Just wait for their first beta, I won't be surprised if they surpass Linux in popularity really soon after that...
Post Edit: Found it! Look at section Support Database, it's the web place to go look for whether a particular piece of hardware of some program works on ReactOS.