For discussion, I'll assume you have a project directory containing your solution file, a "RealLibrary\RealLibrary.csproj" project file (your "real" library, with the dependencies), and a "MockLibrary\MockLibrary.csproj" file (your "mock" library, with the empty implementations).
If I understand correctly, you want to easily "swap" the MockLibrary for the RealLibrary in your solution, and vice-versa.
The easiest/hackiest way to do this, assuming your solution (and dependent projects) are configured to look for the "RealLibrary.csproj" project, is to rename the "RealLibrary" directory (it doesn't matter to what), and rename the "MockLibrary" directory to "RealLibrary" and rename "MockLibrary.csproj" to "RealLibrary.csproj". This will effectively "trick" your solution and dependent projects into loading the "mock library" even though they are referencing the "real library".
A slightly more complex (and perhaps cleaner) solution is to actually modify your "sln" and "csproj" files to reference "MockLibrary.csproj" instead of "RealLibrary.csproj". In the "sln" file, you'll need to change the path to the project in the section near the top:
Microsoft Visual Studio Solution File, Format Version 10.00
# Visual Studio 2008
Project("{FAE04EC0-301F-11D3-BF4B-00C04F79EFBC}") = "RealLibrary", "RealLibrary\RealLibrary.csproj", "{E1714F9A-E1D9-4132-A561-AE2B4919391C}"
EndProject
You need to change that path "RealLibrary\RealLibrary.csproj" to "MockLibrary\MockLibrary.csproj". If you're going for completeness, you can change the name as well (or perhaps just use a generic name like "Library" for the name).
Likewise, in the dependent csproj files, you'll need to find all instances of the "ProjectReference" node where you reference "RealLibrary.csproj" and modify the path. These sections look like this:
<ProjectReference Include="..\RealLibrary\RealLibrary.csproj">
<Project>{FAE04EC0-301F-11D3-BF4B-00C04F79EFBC}</Project>
<Name>RealLibrary</Name>
</ProjectReference>
You could relatively easily write some scripts to perform this swap. However, I think there's a deeper problem here that can be addressed more directly. I'll post that as a separate answer, but I wanted you to have the actual answer you were looking for first.