From a grammatical point of view the parameters of a function call from an optional expression-list inside parentheses. An expression-list consists of one or more assignment-expression separated by a comma token. A comma can only signify a comma operator where an expression is expected.
The comma operator makes an expression out of an expression, a ,
and an assignment-expression, but an expression involving a comma operator is not itself an assignment-expression so can't appear in an expression-list except where it's a constituent of something that is an assignment-expression.
For example, you can surround any expression (including one using the comma operator) inside parentheses to from a primary-expression which is an assignment-expression and hence valid in an expression-list.
E.g.
postfix-expression where the expression-list consists of two assignment-expression each of which is an identifier.
f( a, b );
postfix-expression where the expression-list consists of a single assignment-expression which is a primary-expression which is a parenthesized expression using the comma operator.
f( (a, b) );