How about
NSString *post = @"key1=val1&key2=val2";
NSData *postData = [post dataUsingEncoding:NSASCIIStringEncoding allowLossyConversion:YES];
NSString *postLength = [NSString stringWithFormat:@"%d", [postData length]];
NSMutableURLRequest *request = [[[NSMutableURLRequest alloc] init] autorelease];
[request setURL:[NSURL URLWithString:@"http://www.nowhere.com/sendFormHere.php"]];
[request setHTTPMethod:@"POST"];
[request setValue:postLength forHTTPHeaderField:@"Content-Length"];
[request setValue:@"application/x-www-form-urlencoded" forHTTPHeaderField:@"Content-Type"];
[request setHTTPBody:postData];
Taken from http://deusty.blogspot.com/2006/11/sending-http-get-and-post-from-cocoa.html .
Thats what I recently used, and it worked fine for me.
Btw, 5 seconds of googling would've let to the same result, using the terms "post request cocoa" ;)