Edit: I provided some headings and divided RFCs by topic. I hope it's more accessible now. It's quite a list, and I wish I could format it any better, but unfortunately, that's about it.
Since you mentioned you don't really know what you need, let me clarify:
If you only want to implement a simple "proxy" server that sits in between your MUA (email client) and "real" server, you can probably get away with only implementing basic SMTP functionality. This will allow you to send messages, i.e. to submit messages to an MTA.
POP3 is for email clients to pull messages off of your server, while IMAP is an alternative to POP3 with a somewhat different feature set, mainly providing an on- or offline mode which can be thought of like managing remote folders (i.e. mailboxes).
MIME specifies the format of the contents of e-mail messages in presence of multi-part messages, attachments etc.
Internet Message format (also defines e-mail address format)
http://www.faqs.org/rfcs/rfc822.html
http://www.faqs.org/rfcs/rfc2822.html
SMTP:
http://www.faqs.org/rfcs/rfc821.html
Update to SMTP/RF821:
http://www.faqs.org/rfcs/rfc5321.html
SMTP-AUTH:
http://www.faqs.org/rfcs/rfc2554.html
Message submission (i.e. for the application to be acting as a MUA):
http://www.faqs.org/rfcs/rfc2476.html
IMAPv4:
http://www.faqs.org/rfcs/rfc1730.html
IMAPv4rev1:
http://www.faqs.org/rfcs/rfc2060.html
POP3:
http://www.faqs.org/rfcs/rfc1081.html
http://www.faqs.org/rfcs/rfc1939.html
http://www.faqs.org/rfcs/rfc1957.html
POP3 extensions:
http://www.faqs.org/rfcs/rfc2449.html
Authorization for POP/IMAP:
http://www.faqs.org/rfcs/rfc2195.html
TLS for POP3 and IMAP:
http://www.faqs.org/rfcs/rfc2595.html
AUTH-RESP-CODE for POP3:
http://www.faqs.org/rfcs/rfc3206.html
POP3 simple authentification:
http://www.faqs.org/rfcs/rfc5034.html
MIME, which is composed of 5 RFCs:
http://www.faqs.org/rfcs/rfc2045.html
http://www.faqs.org/rfcs/rfc2046.html
http://www.faqs.org/rfcs/rfc2047.html
http://www.faqs.org/rfcs/rfc4288.html
http://www.faqs.org/rfcs/rfc4289.html
http://www.faqs.org/rfcs/rfc2049.html