I am forced to use Visual Source Safe at my current job. Yes I know, It's like a stick in the eye. But VSS won't go away, VSS is here to stay.
I was wondering if there is any way to do something similar to Subversion's Post-Commit hooks in VSS? Coupled with a few deployment scripts, this would make our lives much, much easier.
No, there isn't. You might be able to get something like that with a third party provider like Source Offsite or something (google it).
If VSS is "here to stay" at your company, then I think you have some bigger issues to deal with over there than just VSS, especially since you can get everything you need for source control for $0.00 with SVN.