As somebody involved personally, the most important thing to me in this release is improved maintainability.
As you certainly know, the Perl core comes with many modules that are also available separately from the CPAN. Historically, it's been a large amount of work (stemmed by Steve Peters among others) to keep the CPAN releases in sync with core. In this release, Nicholas Clark (and others) have put in a lot of work to put these so-called dual-lived modules each in a directory of their own which closely mimics the structure of their CPAN counterpart. While that sounds like a trivial change (and from the user POV, it is), this required shuffling of many, many files, significant changes to the build process, and removal of various codepaths pertaining to whether the given file was being executed as part of core or CPAN (a good thing, naturally).
Furthermore, 5.11.0 has a tiny, tiny change that is quite important to me. If you put "use 5.11.0;" at the top of your code, it will automatically enable "strict". It's a minor detail, but it's been tough to get this in since it's sort of a policy change. We're emphasizing maintainability and encouragement of good practices. In short, making it a better language for the next hundred years (pun intended).