Just to complete your own answer by the gcc documentation about these builtin vectors:
The types defined in this manner can be used with a subset of normal C
operations. Currently, GCC will allow using the following operators on
these types: `+, -, *, /, unary minus, ^, |, &, ~'.
It is probably a good idea to always stick to these when possible. With very high chances gcc will always provide the most efficient code for this SSE stuff.
For your compiler options, add something more specific to your architecture, something like -march=native
will do in most cases.